Silver-catalyzed formal [3+2]-cycloaddition of α-trifluoromethylated methyl isocyanides: a facile stereoselective synthesis of CF3-substituted heterocycles-Reference-Cited by-同舟云学术

Silver-catalyzed formal [3+2]-cycloaddition of α-trifluoromethylated methyl isocyanides: a facile stereoselective synthesis of CF3-substituted heterocycles

Published:2017 Issue:16 Volume:53 Page:2427-2430
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Zhang Xue¹²³⁴⁵,Wang Xin⁶⁷⁸⁹,Gao Yuelei⁶⁷⁸⁹,Xu Xianxiu¹²³⁴⁵^ORCID

Affiliation:

1. College of Chemistry

2. Chemical Engineering and Materials Science

3. Key Laboratory of Molecular and Nano Probes

4. Ministry of Education

5. Shandong Normal University

6. Department of Chemistry

7. Northeast Normal University

8. Changchun 130024

9. China

Abstract

An Ag-catalyzed formal [3+2]-cycloaddition of α-trifluoromethylated methyl isocyanides with polar double bonds has been developed for the expeditious synthesis of trifluoromethylated oxazolines, imidazolines and pyrrolines under mild conditions.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CC/C6CC10124K

Reference51 articles.

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2. Electrophilic Trifluoromethylation by Use of Hypervalent Iodine Reagents

3. Good Partnership between Sulfur and Fluorine: Sulfur-Based Fluorination and Fluoroalkylation Reagents for Organic Synthesis

4. Polyfluorinated Ethanes as Versatile Fluorinated C2-Building Blocks for Organic Synthesis

5. Trifluoromethyltrimethylsilane: Nucleophilic Trifluoromethylation and Beyond

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