Synthesis, molecular and electronic structure of a stacked half-sandwich dititanium complex incorporating a cyclic π-faced bridging ligand-Reference-Cited by-同舟云学术

Synthesis, molecular and electronic structure of a stacked half-sandwich dititanium complex incorporating a cyclic π-faced bridging ligand

Published:2016 Issue:96 Volume:6 Page:94149-94159
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Gyepes Róbert¹²³⁴⁵,Pinkas Jiří⁶⁷⁸⁹,Císařová Ivana¹⁰¹¹¹²¹³⁹,Kubišta Jiří⁶⁷⁸⁹,Horáček Michal⁶⁷⁸⁹,Mach Karel⁶⁷⁸⁹

Affiliation:

1. J. Selye University

2. Department of Chemistry

3. Faculty of Education

4. 945 01 Komárno

5. Slovak Republic

6. J. Heyrovský Institute of Physical Chemistry

7. Academy of Sciences of the Czech Republic, v.v.i.

8. 182 23 Prague 8

9. Czech Republic

10. Department of Inorganic Chemistry

11. Faculty of Science

12. Charles University in Prague

13. 128 40 Prague 2

Abstract

The thermally robust ground singlet state complex [bis(η⁵-pentamethylcyclopentadienyltitanium)-μ-(η⁴:η⁴-1,2,4,5-tetrakis(trimethylsilyl)cyclohexa-1-4-diene-3,6-diyl)] (3) arises from thermolysis of Cp*TiMe₃.

Funder

Grantová Agentura České Republiky

Vedecká Grantová Agentúra MŠVVaŠ SR a SAV

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA14940E

Reference51 articles.

1. Titanacycles derived from reductive coupling of nitriles, alkynes, acetaldehyde, and carbon dioxide with bis(pentamethylcyclopentadienyl)(ethylene)titanium(II)

2. Complexes acetyleniques de titane(II). Reactivite vis-a-vis de l'hydrogene moleculaire: Une nouvelle approche du titanocene

3. Complex of titanocene with tolane. Isolation, spectral characteristics, reactivity

4. The Titanocene Complex of Bis(trimethylsilyl)acetylene: Synthesis, Structure, and Chemistry

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