The peculiar behavior of the molecular dynamics of a glass-forming liquid confined in native porous materials – the role of negative pressure-Reference-Cited by-同舟云学术

The peculiar behavior of the molecular dynamics of a glass-forming liquid confined in native porous materials – the role of negative pressure

Published:2016 Issue:34 Volume:18 Page:23709-23714
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Tarnacka Magdalena¹²³⁴⁵,Kipnusu Wycliffe K.⁶⁷⁸⁹¹⁰,Kaminska Ewa¹¹¹²¹³¹⁴⁴,Pawlus Sebastian¹²³⁴⁵,Kaminski Kamil¹²³⁴⁵,Paluch Marian¹²³⁴⁵

Affiliation:

1. Institute of Physics

2. University of Silesia

3. 40-007 Katowice

4. Poland

5. Silesian Center for Education and Interdisciplinary Research

6. Institute of Experimental Physics I

7. University of Leipzig

8. 04103 Leipzig

9. Germany

10. Leibniz Institute of Surface Modification (IOM)

11. Department of Pharmacognosy and Phytochemistry

12. Medical University of Silesia in Katowice

13. School of Pharmacy with the Division of Laboratory Medicine in Sosnowiec

14. 41-200 Sosnowiec

Abstract

A combination of PALS and BDS data revealed the development of negative pressure, due to vitrification of the interfacial molecules, and the behavior of the confined samples can be predicted from E_V/H_p of the bulk material.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CP/C6CP03923E

Reference48 articles.

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3. On the Statistical Thermodynamics of Spherical and Chain Molecule Fluids

4. Nature of the Glass Transition and the Glassy State

5. Chain Stiffness and the Lattice Theory of Polymer Phases

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