A redox-economical synthesis of trifluoromethylated enamides with the Langlois reagent-Reference-Cited by-同舟云学术

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A redox-economical synthesis of trifluoromethylated enamides with the Langlois reagent

Published:2017 Issue:8 Volume:15 Page:1771-1775
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Yang Hai-Bin¹²³⁴,Selander Nicklas¹²³⁴^ORCID

Affiliation:

1. Department of Organic Chemistry Stockholm University

2. Arrhenius Laboratory

3. SE-106 91 Stockholm

4. Sweden

Abstract

A copper-catalyzed trifluoromethylation of ketoxime acetates employing the Langlois reagent and the N–O bond as an internal oxidant is presented.

Funder

Carl Tryggers Stiftelse för Vetenskaplig Forskning

Wenner-Gren Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/OB/C7OB00203C

Reference76 articles.

1. Rhodium-Catalyzed One-Pot Synthesis of Substituted Pyridine Derivatives from α,β-Unsaturated Ketoximes and Alkynes

2. Palladium-Catalyzed Alkenylation of Quinoline-N-oxides via C−H Activation under External-Oxidant-Free Conditions

3. Palladium-Catalyzed Annulation of Acyloximes with Arynes (or Alkynes): Synthesis of Phenanthridines and Isoquinolines

4. Palladium-Catalyzed Amination of Aromatic C−H Bonds with Oxime Esters

5. Rhodium(III)-Catalyzed Synthesis of Isoquinolines from Aryl KetoneO-Acyloxime Derivatives and Internal Alkynes

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