Assessing long-range contributions to the charge asymmetry of ion adsorption at the air

Assessing long-range contributions to the charge asymmetry of ion adsorption at the air–water interface

Published:2020 Issue:43 Volume:11 Page:11791-11800
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Cox Stephen J.¹²³⁴^ORCID,Thorpe Dayton G.⁵⁶⁷⁸⁹,Shaffer Patrick R.¹¹⁰⁷⁸,Geissler Phillip L.⁵⁶⁷⁸¹

Affiliation:

1. Department of Chemistry

2. University of Cambridge

3. Cambridge CB2 1EW

4. UK

5. Chemical Sciences Division

6. Lawrence Berkeley National Laboratory

7. Berkeley

8. USA

9. Department of Physics

10. University of California

Abstract

Cations and anions have different affinities for the air-water interface. The intrinsic orientation of surface molecules suggests such an asymmetry, but the bias is dominated by solvent response that is spatially local and significantly nonlinear.

Funder

Basic Energy Sciences

Royal Commission for the Exhibition of 1851

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/SC/D0SC01947J

Reference78 articles.

1. Specific Ion Effects at the Air/Water Interface

2. Progress in Modeling of Ion Effects at the Vapor/Water Interface

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4. Unified Molecular Picture of the Surfaces of Aqueous Acid, Base, and Salt Solutions

5. Enhanced Concentration of Polarizable Anions at the Liquid Water Surface: SHG Spectroscopy and MD Simulations of Sodium Thiocyanide

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