Optimizing the ORR activity of Pd based nanocatalysts by tuning their strain and particle size

Author:

Xiao Weiping12345,Liutheviciene Cordeiro Marco Aurelio6789,Gong Mingxing12345,Han Lili101112,Wang Jie12345,Bian Ce12345,Zhu Jing12345,Xin Huolin L.6789,Wang Deli12345ORCID

Affiliation:

1. Key Laboratory of Material Chemistry for Energy Conversion and Storage (Huazhong University of Science and Technology)

2. Ministry of Education

3. Hubei Key Laboratory of Material Chemistry and Service Failure

4. School of Chemistry and Chemical Engineering

5. Huazhong University of Science and Technology

6. Center for Functional Nanomaterials

7. Brookhaven National Laboratory

8. Upton

9. USA

10. School of Materials Science and Engineering Tianjin University

11. Tianjin

12. P. R. China

Abstract

The Fe2O3 shell is in situ formed during the thermal annealing treatment and could effectively prevent the coalescence of Pd2FeCo nanoparticles. Moreover, Pd2FeCo@Pt/C exhibited excellent ORR and Zn–air battery performance, implying that the surface Pt plays an important role in enhancing the activity as well as preventing degradation.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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