A catalyst-controlled switchable reaction of β-keto acids to silyl glyoxylates
Author:
Affiliation:
1. Department of Chemistry
2. Huaibei Normal University
3. Huaibei
4. P.R. China
5. State Key Laboratory of Organometallic Chemistry
Abstract
A catalyst-controlled switchable reaction of β-keto acids to silyl glyoxylates was developed and the decarboxylative-addition products were generated by using a thiourea catalyst.
Funder
National Natural Science Foundation of China
Natural Science Foundation of Anhui Province
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/OB/C8OB00740C
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4. Dye-sensitized photooxidation of silyl diazo compounds. Intramolecular oxygen transfer of carbonyl oxides
5. M. Sasaki and K.Takeda , Brook Rearrangement, Molecular Rearrangements in Organic Synthesis , ed. C. M. Rojas , Wiley , 2015 , ch. 6, pp. 151–183
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