Increasing the oxidation power of TCNQ by coordination of B(C6F5)3-Reference-Cited by-同舟云学术

Increasing the oxidation power of TCNQ by coordination of B(C₆F₅)₃

Published:2022 Issue:32 Volume:58 Page:4958-4961
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Albrecht Paul Anton¹^ORCID,Rupf Susanne Margot¹^ORCID,Sellin Malte¹²^ORCID,Schlögl Johanna¹^ORCID,Riedel Sebastian¹^ORCID,Malischewski Moritz¹^ORCID

Affiliation:

1. Freie Universität Berlin, Institute of Chemistry and Biochemistry, Fabeckstr. 34-36, 14195 Berlin, Germany

2. Albert-Ludwigs-Universität Freiburg, Institute of Inorganic and Analytical Chemistry, Albertstraße 21, 79104 Freiburg, Germany

Abstract

A mixture of TCNQ and four equivalents of B(C6F5)3 is strongly oxidizing and readily forms the new weakly-coordinating anions [TCNQ·4 B(C6F5)3]− and [TCNQ·4 B(C6F5)3]2−.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC00314G

Reference40 articles.

1. Isolation and structural and electronic characterization of salts of the decamethylferrocene dication

2. Oxidation of closo-[B12Cl12]2− to the Radical Anion [B12Cl12].− and to Neutral B12Cl12

3. Chemical Redox Agents for Organometallic Chemistry

4. Chasing the Mond Cation: Synthesis and Characterization of the Homoleptic Nickel Tetracarbonyl Cation and its Tricarbonyl‐Nitrosyl Analogue

5. Ag[Fe(CO)5]2+: A Bare Silver Complex with Fe(CO)5as a Ligand

Cited by 7 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. From Stable Radicals to Thermally Robust High-Spin Diradicals and Triradicals;Chemical Reviews;2023-10-13

2. The Dynamic Lewis Acid–Carbene Hybrid: Pushing the Electrophilicity of Carbenes to the Limit;Journal of the American Chemical Society;2023-09-29

3. Coordination of Tetracyanoquinodimethane-Derivatives with Tris(pentafluorophenyl)borane Provides Stronger p-Dopants with Enhanced Stability;ACS Applied Materials & Interfaces;2023-09-20

4. Insights into Single-Electron-Transfer Processes in Frustrated Lewis Pair Chemistry and Related Donor–Acceptor Systems in Main Group Chemistry;Chemical Reviews;2023-07-11

5. Lewis Acid‐Mediated Radical Stabilization and Dynamic Covalent Bonding: Tunable, Reversible and Photocontrollable;Angewandte Chemie International Edition;2023-04-12