The intensively enhanced conductivity of polyelectrolytes by amphiphilic compound doping

Author:

Hsu Huang-Ming1234,Hsu Chun-Han1234,Kuo Ping-Lin1234

Affiliation:

1. Department of Chemical Engineering

2. National Cheng Kung University

3. Tainan City

4. Taiwan

Abstract

A simple amphiphilic compound, pyrenesulfonic acid (PSA), interacts with the hydrophobic moiety of a copolymer (sulfonated poly(styrene-b-isoprene-b-styrene), s-SISH) and simultaneously provides hydrophiles of –SO3H. Doping 2% PSA to the membranes of s-SISH enhances its very low conductivity by 26 times from 2.0 × 10−3 S cm−1 to 5.3 × 10−2 S cm−1.

Funder

Ministry of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Reference39 articles.

1. A. J. Appleby and F. R.Foulkes, Fuel cell handbook, Van Nostrand, New York, 1989

2. U.S. Department of Energy , Fuel Cell Handbook, B/T Books, Orinda, CA, 6th edn, 2002

3. A. Eisenberg and M.King, Ion Containing Polymers: Physical Properties and Structure, Academic Press, New York, 1977

4. Ion Percolation and Insulator-to-Conductor Transition in Nafion Perfluorosulfonic Acid Membranes

5. Synthesis and properties of highly sulfonated proton conducting polyimides from bis(3-sulfopropoxy)benzidine diaminesElectronic supplementary information (ESI) available: 1H NMR spectra of BSPB diamines and IR spectra of resulting polyimide membranes. See http://www.rsc.org/suppdata/jm/b3/b313276e/

Cited by 3 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3