Cu-incorporated PtBi intermetallic nanofiber bundles enhance alcohol oxidation electrocatalysis with high CO tolerance

Author:

Zhang Jingxian12,Yuan Menglei12,Zhao Tongkun12,Wang Wenbo1,Huang Haoyang1,Cui Kairui3,Liu Zhanjun24,Li Shuwei12,Li Zehui5,Zhang Guangjin126ORCID

Affiliation:

1. CAS Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, P. R. China

2. Center of Materials Science and Optoeletronics Engineering, University of Chinese Academy of Sciences, 100049, P. R. China

3. Beijing Engineering Research Center of Printed Electronics, Beijing Institute of Graphic Communication, Beijing, 102600, China

4. CAS Key Laboratory of Carbon Materials, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan, 030001, China

5. State Key Laboratory for Mesoscopic Physics, Frontiers Science Center for Nano-optoelectronics, School of Physics, Peking University, Beijing, 100871, China

6. Chemistry and Chemical Engineering Guangdong Laboratory, Shantou, 515031, China

Abstract

One-pot surfactant-free synthesis of 1D intermetallic Cu–PtBi NFBs endow with superior MOR and EOR performance by weakening the bonding strength of CO* on Pt sites and strengthening anchoring of OH* on adjacent Cu sites to optimize reaction pathway.

Funder

China Postdoctoral Science Foundation

Natural Science Foundation of Shandong Province

National Key Research and Development Program of China

Key Program for International S and T Cooperation Projects of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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