A pentacoordinated norbornenyl-acyl-rhodium(iii) complex as a likely intermediate in the catalytic hydroacylation of norbornadiene-Reference-Cited by-同舟云学术

A pentacoordinated norbornenyl-acyl-rhodium(iii) complex as a likely intermediate in the catalytic hydroacylation of norbornadiene

Published:2016 Issue:46 Volume:45 Page:18502-18509
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Almenara N.¹²³⁴,Ibarlucea L.¹²³⁴,Mendicute-Fierro C.¹²³⁴,Seco J. M.¹²³⁴,Rodríguez-Diéguez A.⁵⁶⁷⁴,Garralda M. A.¹²³⁴,Huertos M. A.¹²³⁴⁸^ORCID

Affiliation:

1. Facultad de Química de San Sebastián

2. Universidad del País Vasco (UPV/EHU)

3. San Sebastián

4. Spain

5. Departamento de Química Inorgánica

6. Universidad de Granada

7. 18071 Granada

8. IKERBASQUE

Abstract

The isolated and characterized compounds hydrido-acyl-Rh(iii) and norbornenyl-acyl-Rh(iii) are active species in the hydroacylation of norbornadiene with quinoline-8-carbaldehyde.

Funder

Ikerbasque, Basque Foundation for Science

Secretaría de Estado de Investigación, Desarrollo e Innovación

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT03778J

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