Entropy driven preference for alkene adsorption at the pore mouth as the origin of pore-mouth catalysis for alkane hydroisomerization in 1D zeolites-Reference-Cited by-同舟云学术

Entropy driven preference for alkene adsorption at the pore mouth as the origin of pore-mouth catalysis for alkane hydroisomerization in 1D zeolites

Published:2021 Issue:2 Volume:11 Page:563-574
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Shubin Aleksandr A.¹²³⁴²^ORCID,Zilberberg Igor L.¹²³⁴²^ORCID

Affiliation:

1. Boreskov Institute of Catalysis

2. Novosibirsk 630090

3. Russian Federation

4. Novosibirsk State University

Abstract

This work presents a theoretical basis for a pore-mouth catalysis model developed to explain the positional selectivity of skeletal isomerization on bifunctional metal acid-zeolite catalysts.

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CY/D0CY01485K

Reference27 articles.

1. Monomethyl-Branching of Long n-Alkanes in the Range from Decane to Tetracosane on Pt/H-ZSM-22 Bifunctional Catalyst

2. Evidences for pore mouth and key–lock catalysis in hydroisomerization of long n-alkanes over 10-ring tubular pore bifunctional zeolites

3. Effect of boron on acid and catalytic properties of Pd-ZSM-23/Al2O3 catalysts in the reaction of diesel fuel hydroisomerization

4. Pore mouth physisorption of alkanes on ZSM-22: estimation of physisorption enthalpies and entropies by additivity method

5. Isomer sieving and the selective formation of terminal methyl isomers in reactions of linear alkanes on one-dimensional zeolites

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