Mapping the effect of configuration and protecting group pattern on glycosyl acceptor reactivity-Reference-Cited by-同舟云学术

Mapping the effect of configuration and protecting group pattern on glycosyl acceptor reactivity

Published:2023 Issue:6 Volume:14 Page:1532-1542
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

van Hengst Jacob M. A.¹,Hellemons Rik J. C.¹,Remmerswaal Wouter A.¹,van de Vrande Koen N. A.¹,Hansen Thomas¹²^ORCID,van der Vorm Stefan¹^ORCID,Overkleeft Hermen S.¹^ORCID,van der Marel Gijsbert A.¹^ORCID,Codée Jeroen D. C.¹^ORCID

Affiliation:

1. Leiden University, Leiden Institute of Chemistry, Einsteinweg 55, 2333 CC Leiden, The Netherlands

2. Department of Theoretical Chemistry, Amsterdam Institute of Molecular and Life Sciences (AIMMS), Amsterdam Center for Multiscale Modeling (ACMM), Vrije Universiteit Amsterdam, De Boelelaan 1083, 1081 HV Amsterdam, The Netherlands

Abstract

A systematic series of 67 acceptor glycosides has been used to map structure–reactivity–stereoselectivity principles for glycosyl acceptors.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D2SC06139B

Reference28 articles.

1. Guidelines for O-Glycoside Formation from First Principles

2. A. V.Demchenko , Handbook of Chemical Glycosylation: Advances in Stereoselectivity and Therapeutic Relevance , Wiley-VCH Verlag GmbH & Co. KGaA , 2008

3. A propos of glycosyl cations and the mechanism of chemical glycosylation; the current state of the art