An unusual co-crystal [(μ2-dcpm)Ag2(μ2-O2CH)(η2-NO3)]2·[(μ2-dcpm)2Ag4(μ2-NO3)4] and its connection to the selective decarboxylation of formic acid in the gas phase-Reference-Cited by-同舟云学术

An unusual co-crystal [(μ2-dcpm)Ag2(μ2-O2CH)(η2-NO3)]2·[(μ2-dcpm)2Ag4(μ2-NO3)4] and its connection to the selective decarboxylation of formic acid in the gas phase

Published:2016 Issue:48 Volume:45 Page:19408-19415
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Zavras Athanasios¹²³⁴,White Jonathan M.¹²³⁴,O'Hair Richard A. J.¹²³⁴^ORCID

Affiliation:

1. School of Chemistry and Bio21 Institute of Molecular Science and Biotechnology

2. The University of Melbourne

3. Melbourne

4. Australia

Abstract

Binuclear silver cluster with μ₂-formate and μ₂-dcpm catalyses the decomposition of HCO₂H. This structural motif is present in the crystal.

Funder

Australian Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT03700C

Reference47 articles.

1. Formic acid as a hydrogen source – recent developments and future trends

2. Carbon dioxide and formic acid—the couple for environmental-friendly hydrogen storage?

3. Unimolecular Decomposition of Formic Acid in the Gas PhaseOn the Ratio of the Competing Reaction Channels

4. Computational Study on the Kinetics and Mechanisms for the Unimolecular Decomposition of Formic and Oxalic Acids

5. Catalytic Generation of Hydrogen from Formic acid and its Derivatives: Useful Hydrogen Storage Materials

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