Photoinduced δ electron transfer in phenylene bridged Mo2 dimers

Author:

Cheng Tao1234,Xiao Xuan1564,Zhang Lei7894,Liu Chun Y.12341,Wang Li-Li7894,Meng Miao1234,Zhao Fang7894,Wang Hui7894,Ji Liang-Nian7894

Affiliation:

1. Department of Chemistry

2. Jinan University

3. Guangzhou 510632

4. China

5. Tongji University

6. Shanghai 200092

7. State Key Laboratory of Optoelectronics Material and Technologies

8. Sun Yet-Sen University

9. Guangzhou 510275

Abstract

Femtosecond transient spectroscopic study of [Mo2]–ph–[Mo2] complexes showed that the electron transfer of Mo2(δ*) → Mo2(δ) is faster than that of ph(π*) → Mo2(δ).

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference28 articles.

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2. Nature of biological electron transfer

3. Photosynthetic energy conversion: natural and artificial

4. Towards complete cofactor arrangement in the 3.0 Å resolution structure of photosystem II

5. Intramolecular Long-Distance Electron Transfer in Organic Molecules

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