Photoredox asymmetric catalytic enantioconvergent substitution of 3-chlorooxindoles

Author:

Zeng Guangkuo12345,Li Yunqiang12345,Qiao Baokun12345,Zhao Xiaowei12345,Jiang Zhiyong12345ORCID

Affiliation:

1. Key Laboratory of Natural Medicine and Immuno-Engineering of Henan Province

2. Henan University

3. Jinming Campus

4. Kaifeng

5. P. R. China

Abstract

An enantioconvergent substitution of 3-substituted 3-chlorooxindoles with N-aryl glycines under visible light irradiation is reported.

Funder

National Natural Science Foundation of China

Henan University of Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Reference61 articles.

1. Modern Physical Organic Chemistry , ed. E. V. Anslyn and D. A. Dougherty , University Science Books , Sausalito, CA , 2006

2. S. R. Hartshorn , Aliphatic Nucleophilic Subsitution , Cambridge University Press , London , 1973

3. Transition-Metal Catalysis of Nucleophilic Substitution Reactions: A Radical Alternative to SN1 and SN2 Processes

4. Enantioselective Thiourea-Catalyzed Additions to Oxocarbenium Ions

5. Catalytic Enantioselective Stereoablative Alkylation of 3-Halooxindoles: Facile Access to Oxindoles with C3 All-Carbon Quaternary Stereocenters

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