New routes to molybdenum and tungsten carbyne complexes [M(CO)2(CPh)(η-C5H4R)](M = Mo or W, R = SnPh3; M = W, R = H)
Author:
Publisher
Royal Society of Chemistry (RSC)
Subject
Molecular Medicine
Link
http://pubs.rsc.org/en/content/articlepdf/1995/C3/C39950000515
Reference17 articles.
1. Hydride to carbene migration at molybdenum; the isomerisation of Mo(H){C[CH2]3NMe}(CO)2(η-C5H5) to Mo(CO)2{η2-CH[CH2]3NMe}(η-C5H5)
2. Synthesis and reactions of the tungsten nonheteroatom-stabilised carbene anion [CpW(CO)2(CHPh)]−
3. Hydride to carbene migrations
4. Hydride to carbene migration in the CpMH{=C(NHEt)Ph}(CO)2 (M = Mo, W) system. X-Ray crystal structure of Cp η2-CH(Ph)NHEt (CO)2
5. Hydride to carbene migration in the CpMH{C(OEt)Ph}(CO)2 (M = Mo, W) system and subsequent rearrangement of the consequent products to η3-benzyl complexes. X-Ray crystal structure of the η3-benzyl CpW(CO)2{η3-C6H5CH(OEt)}
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3. Proton Addition to an Anionic Carbene Complex as a Route to Seven-Coordinate Methyl Carbonyl Complexes in Equilibrium with η2-Acyl Complexes;Organometallics;2004-07-31
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