Controlled translocation of palladium(ii) within a 22 ring atom macrocyclic ligand

Author:

Burgess Michael G.123,Naveed Zafar M.12345,Horner Stephen T.123,Clark George R.123,James Wright L.123

Affiliation:

1. School of Chemical Sciences

2. University of Auckland

3. Auckland 1142, New Zealand

4. Chemistry Department

5. University of Gujrat

Abstract

Palladium can be directed to coordinate to the “tail” region of the macrocycle H4L to give 3b. Translocation of the palladium from the tail coordination pocket to the head coordination pocket occurs on treatment with amines such as n-BuNH2 to give 4.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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