Catalyst-free, aza-Michael polymerization of hydrazides: polymerizability, kinetics, and mechanistic origin of an α-effect-Reference-Cited by-同舟云学术

Catalyst-free, aza-Michael polymerization of hydrazides: polymerizability, kinetics, and mechanistic origin of an α-effect

Published:2019 Issue:42 Volume:10 Page:5790-5804
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Love Dillon¹²³⁴^ORCID,Kim Kangmin⁵²³⁴,Domaille Dylan W.⁵⁶⁷⁴^ORCID,Williams Olivia¹²³⁴,Stansbury Jeffrey¹²³⁴⁸,Musgrave Charles¹²³⁴⁵,Bowman Christopher¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemical and Biological Engineering

2. University of Colorado Boulder

3. Boulder

4. USA

5. Department of Chemistry

6. Colorado School of Mines

7. Golden

8. Materials Science and Engineering Program

Abstract

α-Effect observed in unsubstituted hydrazide nucleophiles imbues highly efficient bis-addition reactivity in the aza-Michael reaction of hydrazides, in contrast to primary alkyl amines.

Funder

National Science Foundation

National Institutes of Health

U.S. Department of Education

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2019/PY/C9PY01199D

Reference89 articles.

1. Recent contributions from the asymmetric aza-Michael reaction to alkaloids total synthesis