Formation of a cyclooctatetraenylsamarium(<scp>iii</scp>) inverse sandwich that ring-opens tetrahydrofuran-Reference-Cited by-同舟云学术

Formation of a cyclooctatetraenylsamarium(iii) inverse sandwich that ring-opens tetrahydrofuran

Published:2023 Issue:12 Volume:52 Page:3563-3566
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Peedika Paramban Ramees¹^ORCID,Guo Zhifang¹,Deacon Glen B.²^ORCID,Junk Peter C.¹^ORCID

Affiliation:

1. College of Science & Engineering, James Cook University, Townsville, QLD, 4811, Australia

2. School of Chemistry, Monash University, Clayton, VIC, 3800, Australia

Abstract

Reductive trapping of the cyclooctatetraenyl dianion by treatment of [Sm(DippForm)2(thf)2] {DippFormH = N,N′-bis(2,6-diisopropylphenyl)formamidine} with cyclooctatetraene in toluene yields an inverse sandwich dinuclear complex [Sm2(DippForm)4(COT)].

Funder

Australian Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D2DT04164B

Reference39 articles.

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