Microsecond 3MLCT excited state lifetimes in bis-tridentate Ru(ii)-complexes: significant reductions of non-radiative rate constants-Reference-Cited by-同舟云学术

Microsecond 3MLCT excited state lifetimes in bis-tridentate Ru(ii)-complexes: significant reductions of non-radiative rate constants

Published:2017 Issue:39 Volume:46 Page:13314-13321
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Abrahamsson Maria¹²³⁴^ORCID,Becker Hans-Christian¹²³⁴,Hammarström Leif¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry - Ångström Laboratory

2. Uppsala University

3. SE-751 20 Uppsala

4. Sweden

Abstract

A close to octahedral structure and an unusually small singlet–triplet mixing result in microsecond ³MLCT excited state lifetimes for this class of tridentate Ru(ii)-complexes.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT02437A

Reference60 articles.

1. Octahedral Fe(II) and Ru(II) Complexes Based on a New Bis 1,10-Phenanthroline Ligand That Imposes a Well Defined Axis

2. Ruthenium(II) and Osmium(II) Bis(terpyridine) Complexes in Covalently-Linked Multicomponent Systems: Synthesis, Electrochemical Behavior, Absorption Spectra, and Photochemical and Photophysical Properties

3. Synthesis and properties of mono- and oligo-nuclear Ru(II) complexes of tridentate ligands: The quest for long-lived excited states at room temperature

4. Designing tridentate ligands for ruthenium(ii) complexes with prolonged room temperature luminescence lifetimes

5. Expanded bite angles in tridentate ligands. Improving the photophysical properties in bistridentate RuII polypyridine complexes

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