Operando exploration of tribochemical decomposition in synthetic FeS2 thin film and mineral iron pyrite

Author:

Muñoz-Cortés E.1ORCID,Sánchez-Prieto J.2ORCID,Zabala B.3ORCID,Sanchez C.14ORCID,Flores E.5ORCID,Flores A.6ORCID,Roman E.7,Ares J. R.1ORCID,Nevshupa R.8ORCID

Affiliation:

1. MIRE-group, Departamento de Física de Materiales, Facultad de Ciencias, Universidad Autónoma de Madrid, Madrid 28049, Spain

2. Centre for Micro Analysis of Materials, Universidad Autónoma de Madrid, C/ Faraday 3, Madrid 28049, Spain

3. Materials and Tribology Unit, Tekniker, C/ I. Goenaga 5, Eibar 20600, Spain

4. Instituto Nicolás Cabrera, Universidad Autónoma de Madrid, Francisco Tomás y Valiente 7, Madrid 28049, Spain

5. Departamento de Física Aplicada, Centro de Investigación y de Estudios Avanzados (CINVESTAV), Merida 97310, Mexico

6. Departamento de Física de Polímeros, Elastómeros y Aplicaciones Energéticas, Instituto de Ciencia y Tecnología de Polímeros (ICTP), CSIC, C/ Juan de la Cierva 3, Madrid 28006, Spain

7. Institute of Materials Science of Madrid (ICMM), CSIC, C/ Sor Juan Inés de la Cruz 3, Madrid 28048, Spain

8. Eduardo Torroja Institute of Construction Sciences (IETCC), CSIC, C/ Serrano Gal-vache 4, Madrid 28033, Spain

Abstract

The tribochemical decomposition of iron pyrite at room temperature involves rich solid-state reactions of FeS2 with impurities such as hydrogen, oxygen and carbon and is controlled by the concentrations of precursors.

Funder

Dirección General de Universidades e Investigación

Ministerio de Ciencia e Innovación

European Regional Development Fund

European Social Fund Plus

Publisher

Royal Society of Chemistry (RSC)

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