A computational investigation of orbital overlap versus energy degeneracy covalency in [UE2]2+ (E = O, S, Se, Te) complexes-Reference-Cited by-同舟云学术

登录注册会员服务联系我们

A computational investigation of orbital overlap versus energy degeneracy covalency in [UE2]2+ (E = O, S, Se, Te) complexes

Published:2020 Issue:4 Volume:49 Page:1077-1088
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Platts James A.¹²³⁴^ORCID,Baker Robert J.¹⁵⁶⁷⁸^ORCID

Affiliation:

1. School of Chemistry

2. Cardiff University

3. Cardiff CF10 3AT

4. UK

5. University of Dublin

6. Trinity College

7. Dublin 2

8. Ireland

Abstract

Covalency in analogues of uranyl with heavy chalcogens is explored using DFT, and traced to increased energy-degeneracy as the group is descended.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/C9DT04484A

Reference69 articles.

1. F. A. Cotton , G.Wilkinson , C. A.Murillo and M.Bochmann , Advanced Inorganic Chemistry , Wiley , 6th edn, 1999

2. An Ion-exchange Study of Possible Hybridized 5f Bonding in the Actinides1

3. Two isostructural actinide .pi. complexes. Crystal and molecular structure of bis(cyclooctatetraenyl)uranium(IV), U(C8H8)2, and bis(cyclooctatetraenyl)thorium(IV), Th(C8H8)2

4. Bis(.eta.8-1,3,5,7-tetramethylcyclooctatetraene) compounds of protactinium, neptunium, and plutonium

5. Bis(cyclooctatetraenyl)uranium (uranocene). A new class of sandwich complexes that utilize atomic f orbitals

Cited by 20 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Proton-Coupled Electron Transfer at the Pu^5+/4+ Couple;Journal of the American Chemical Society;2024-07-25

2. Stability of the Protactinium(V) Mono‐Oxo Cation Probed by First‐Principle Calculations;Chemistry – A European Journal;2024-02-21

3. Actinide inverse trans influence versus cooperative pushing from below and multi-center bonding;Nature Communications;2023-07-18

4. Bonding of isovalent homologous actinide and lanthanide pairs with chalcogenide donors: effect of metal f-orbital participation and donor softness;Structural Chemistry;2022-12-05

5. Linearity and Chemical Bond of UO₂²⁺ Revisited: A Comparison Study with UN₂ and UE₂²⁺ (E = S, Se, and Te) Based on Relativistic Calculations;The Journal of Physical Chemistry A;2022-11-14

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线，采集、加工和组织学术论文而形成的新型学术文献查询和分析系统，可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容，当前同舟云学术共收录了国内外主流学术期刊6万余种，收集的期刊论文及会议论文总量共计约1.5亿篇，并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询！咨询电话：010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号京ICP备18003416号-3