Understanding the size effects on the electronic structure of ThO2 nanoparticles

Author:

Amidani Lucia12345ORCID,Plakhova Tatiana V.6789ORCID,Romanchuk Anna Yu.6789ORCID,Gerber Evgeny12345ORCID,Weiss Stephan5101112,Efimenko Anna13234,Sahle Christoph J.13234ORCID,Butorin Sergei M.1415161718ORCID,Kalmykov Stepan N.6789ORCID,Kvashnina Kristina O.12345ORCID

Affiliation:

1. The Rossendorf Beamline at ESRF – The European Synchrotron

2. CS40220

3. 38043 Grenoble Cedex 9

4. France

5. Helmholtz Zentrum Dresden-Rossendorf (HZDR)

6. Department of Chemistry

7. Lomonosov Moscow State University

8. Moscow

9. Russian Federation

10. Institute of Resource Ecology

11. 01314 Dresden

12. Germany

13. ESRF – The European Synchrotron

14. Molecular and Condensed Matter Physics

15. Department of Physics and Astronomy

16. Uppsala University

17. Uppsala

18. Sweden

Abstract

High-resolution XANES spectra of small ThO2 nanoparticles show the signature of the more exposed Th atoms at the surface.

Funder

Russian Foundation for Basic Research

H2020 European Research Council

Vetenskapsrådet

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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