Rhenium versus cadmium: an alternative structure for a thermally stable cadmium carbonyl compound

Author:

Amemiya Erika1234,Loo Aaron1234,Shlian Daniel G.1234,Parkin Gerard1234ORCID

Affiliation:

1. Department of Chemistry

2. Columbia University

3. New York

4. USA

Abstract

The previously reported novel cadmium carbonyl compound, [Cd(CO)3(C6H3Cl)]4, is better formulated as the rhenium compound, [Re(CO)3(C4N2H3S)]4.

Funder

Basic Energy Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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4. J. F. Hartwig , Organotransition Metal Chemistry: From Bonding to Catalysis , University Science Books , Sausalito , 2009

5. Trends in Molecular Geometries and Bond Strengths of the Homoleptic d10 Metal Carbonyl Cations [M(CO)n]x+ (Mx+=Cu+, Ag+, Au+, Zn2+, Cd2+, Hg2+;n=1-6): A Theoretical Study

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