Reaction of FcCCC(O)R (Fc = ferrocenyl) with Ru3(CO)12 leading to unexpected nitro-group reduced ruthenoles and 1,2-CO-inserted triruthenium clusters
Author:
Affiliation:
1. Key Laboratory of Applied Surface and Colloid Chemistry
2. MOE/School of Chemistry and Chemical Engineering
3. Shaanxi Normal University
4. Xi'an 710062
5. China
Abstract
Unexpected nitro-group reduced ruthenoles and 1,2-CO-inserted π-coordinated triruthenium clusters were isolated during the reactions of Ru3(CO)12 with ferrocene-containing 1,3-ynones.
Funder
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/RA/C8RA04548H
Reference72 articles.
1. A Novel Chelation-Assisted Hydroesterification of Alkenes via Ruthenium Catalysis
2. Ru3(CO)12-Catalyzed Silylation of Benzylic C−H Bonds in Arylpyridines and Arylpyrazoles with Hydrosilanes via C−H Bond Cleavage
3. Catalytic Synthesis of Tricyclic Quinoline Derivatives from the Regioselective Hydroamination and C−H Bond Activation Reaction of Benzocyclic Amines and Alkynes
4. Recyclable Solid Ruthenium Catalysts Supported on Metal Oxides for the Addition of Carboxylic Acids to Terminal Alkynes
5. Ruthenium-Catalyzed Regioselective [2 + 2 + 2] Cyclotrimerization of Trifluoromethyl Group Substituted Internal Alkynes
Cited by 3 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献
1. Revisiting reactions of alkynes with Ru3(CO)12: Effects of alkyne substituents and solvents on the structures of ruthenium cluster products;Inorganica Chimica Acta;2019-01
2. Unexpected formation and conversion: role of substituents of 1,3-ynones in the reactivity and product distribution during their reactions with Ru3(CO)12;New Journal of Chemistry;2019
3. Activation reactions of 2-pyridyl and 2-pyrimidinyl alkynes with Ru3(CO)12;New Journal of Chemistry;2019
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