Radical revelations: the pnictogen effect in linear acetylenes-Reference-Cited by-同舟云学术

Radical revelations: the pnictogen effect in linear acetylenes

Published:2024 Issue:9 Volume:26 Page:7718-7730
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Gallegos Miguel¹,del Amo Vicente²^ORCID,Guevara-Vela José Manuel³^ORCID,Moreno-Alcántar Guillermo⁴^ORCID,Martín Pendás Ángel¹^ORCID

Affiliation:

1. Departamento de Química Física y Analítica, Universidad de Oviedo, Oviedo E-33006, Spain

2. Departamento de Química Orgánica e Inorgánica, Universidad de Oviedo, Oviedo E-33006, Spain

3. Departamento de Química Física Aplicada, Universidad Autónoma de Madrid, Madrid E-28049, Spain

4. Department of Chemistry, School of Natural Sciences, Technical University of Munich, Lichtenbergstr. 4, Garching b., München 85748, Germany

Abstract

Acetylenes are crucial in chemistry. Adding heteroatoms like pnictogens changes their properties. This study explores how these changes affect dipnictogenoacetylenes (DXAs), offering insights into potential new routes for free-radical chemistry.

Funder

Ministerio de Ciencia e Innovación

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CP/D3CP06324K

Reference67 articles.

1. Main Group Multiple Bonds for Bond Activations and Catalysis

2. Chemical substructures that enrich for biological activity

3. A Stable Compound Containing a Silicon-Silicon Triple Bond

4. Nonclassical double-bridged structure in silicon-containing molecules: Experimental evidence in Si_{2}H_{2} from its submillimeter-wave spectrum

5. Butterfly, Vinylidene‐Like, Monobridged and Trans Structures of Si₂H₂⁺: Comparison to the Well‐Characterized Neutral Si₂H₂