Questing for homoleptic mononuclear manganese complexes with monodentate O-donor ligands

Author:

Pérez-Bitrián Alberto12ORCID,Munárriz Julen3ORCID,Krause Konstantin B.2,Schlögl Johanna1,Hoffmann Kurt F.1,Sturm Johanna S.1,Hadi Amiera N.1,Teutloff Christian4ORCID,Wiesner Anja1,Limberg Christian2ORCID,Riedel Sebastian1ORCID

Affiliation:

1. Fachbereich Biologie, Chemie, Pharmazie, Institut für Chemie und Biochemie − Anorganische Chemie, Freie Universität Berlin, Fabeckstraße 34/36, Berlin 14195, Germany

2. Institut für Chemie, Humboldt-Universität zu Berlin, Brook-Taylor-Straße 2, Berlin 12489, Germany

3. Departamento de Química Física and Instituto de Biocomputación y Física de Sistemas Complejos (BIFI), Universidad de Zaragoza, Pedro Cerbuna 12, Zaragoza 50009, Spain

4. Fachbereich Physik, Freie Universität Berlin, Arnimallee 14, Berlin 14195, Germany

Abstract

High spin monomeric complexes [MnII(OTeF5)4]2− and [MnIII(OTeF5)5]2− represent novel homoleptic coordination environments at Mn(ii) and Mn(iii) centers with monodentate O-donor ligands.

Funder

Freie Universität Berlin

Deutsche Forschungsgemeinschaft

Alexander von Humboldt-Stiftung

Ministerio de Ciencia e Innovación

Verband der Chemischen Industrie

Publisher

Royal Society of Chemistry (RSC)

Reference91 articles.

1. E.Salomon , N.Keren , M.Kanteev and N.Adir , in The Chemistry of Organomanganese Compounds , Belonging to Patai's Chemistry of Functional Groups, ed. I. Marek and Z. Rappoport , Wiley , Chichester , 2011 , pp. 289–304

2. The Possible Role of Proton-Coupled Electron Transfer (PCET) in Water Oxidation by Photosystem II

3. Water-Splitting Chemistry of Photosystem II

4. Recent pulsed EPR studies of the Photosystem II oxygen-evolving complex: implications as to water oxidation mechanisms

5. Manganese Clusters with Relevance to Photosystem II

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