Affiliation:
1. School of Chemistry, University of Glasgow, G12 8QQ, UK
Abstract
Heating unsaturatedN2-sulfonyl amidines with BF2OTf in acetonitrile transformed them into stereodefined cyclic amidines. Investigating by-products of the reaction suggested a fascinating mechanism including 1,7-H shift and electrocyclisation.
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis