Exploring antiaromaticity in single-molecule junctions formed from biphenylene derivatives

Author:

Gantenbein Markus1234,Li Xiaohui56789ORCID,Sangtarash Sara1011124ORCID,Bai Jie56789ORCID,Olsen Gunnar1234ORCID,Alqorashi Afaf1011124,Hong Wenjing56789ORCID,Lambert Colin J.1011124ORCID,Bryce Martin R.1234ORCID

Affiliation:

1. Department of Chemistry

2. Durham University

3. Durham

4. UK

5. State Key Laboratory of Physical Chemistry of Solid Surfaces

6. NEL

7. iChEM

8. College of Chemistry and Chemical Engineering, Xiamen University

9. Xiamen 361005

10. Department of Physics

11. Lancaster University

12. Lancaster

Abstract

We report the synthesis of a series of oligophenylene-ethynylene (OPE) derivatives with biphenylene core units, designed to assess the effects of biphenylene antiaromaticity on charge transport in molecular junctions.

Funder

H2020 Future and Emerging Technologies

Engineering and Physical Sciences Research Council

National Basic Research Program of China

National Natural Science Foundation of China

Leverhulme Trust

Teknologi og Produktion, Det Frie Forskningsråd

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

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