Inducing selectivity and chirality in group IV metal coordination with high-denticity hydroxypyridinones
Author:
Affiliation:
1. Chemical Sciences Division
2. Lawrence Berkeley National Laboratory
3. Berkeley
4. USA
5. Department of Chemistry
6. Department of Nuclear Engineering
Abstract
Hydroxypyridinone ligand 3,4,3-LI(1,2-HOPO) exhibits remarkable charge-based selectivity for octacoordinated tetravalent cations, forming stable chiral complexes over a very broad pH range.
Funder
Basic Energy Sciences
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT01031A
Reference43 articles.
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4. Toxic heavy metal – Pb, Cd, Sn – complexation by the octadentate hydroxypyridinonate ligand archetype 3,4,3-LI(1,2-HOPO)
5. Highly Luminescent and Stable Hydroxypyridinonate Complexes: A Step Towards New Curium Decontamination Strategies
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