Stepped spin crossover in Fe(iii) halogen substituted quinolylsalicylaldimine complexes-Reference-Cited by-同舟云学术

Stepped spin crossover in Fe(iii) halogen substituted quinolylsalicylaldimine complexes

Published:2014 Issue:46 Volume:43 Page:17509-17518
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Phonsri Wasinee¹²³⁴⁵,Harding David J.¹²³⁴,Harding Phimphaka¹²³⁴,Murray Keith S.⁵⁶⁷,Moubaraki Boujemaa⁵⁶⁷,Gass Ian A.⁵⁶⁷⁸⁹,Cashion John D.¹⁰⁶⁷,Jameson Guy N. L.¹¹¹²¹³,Adams Harry¹⁴¹⁵¹⁶

Affiliation:

1. Molecular Technology Research Unit Cell

2. School of Science

3. Walailak University

4. Thasala, Thailand

5. School of Chemistry

6. Monash University

7. Clayton, Melbourne, Australia

8. Now at the School of Pharmacy and Biomolecular Sciences

9. University of Brighton

10. School of Physics

11. Department of Chemistry & MacDiarmid Institute for Advanced Materials and Nanotechnology

12. University of Otago

13. Dunedin 9054, New Zealand

14. Department of Chemistry

15. University of Sheffield

16. Sheffield, UK

Abstract

Four iron(iii) spin crossover complexes with halogen substituted ligands are reported. The halogen is correlated with T_1/2 and controls the degree of spin crossover while extensive C–H⋯X and X⋯π interactions increase cooperativity.

Funder

Thailand Research Fund

National Science and Technology Development Agency

Australian Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT01701C

Reference42 articles.

1. Spin Crossover—An Overall Perspective