Contrasting photophysical properties of rhenium(i) tricarbonyl complexes having carbazole groups attached to the polypyridine ligand-Reference-Cited by-同舟云学术

Contrasting photophysical properties of rhenium(i) tricarbonyl complexes having carbazole groups attached to the polypyridine ligand

Published:2016 Issue:29 Volume:45 Page:11688-11698
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Ramos L. D.¹²³,Sampaio R. N.⁴⁵⁶,de Assis F. F.⁷⁸⁹,de Oliveira K. T.⁷⁸⁹,Homem-de-Mello P.¹²³,Patrocinio A. O. T.⁴⁵⁶,Frin K. P. M.¹²³

Affiliation:

1. Universidade Federal do ABC - UFABC

2. Santo Andre

3. 09210-170 Brazil

4. Universidade Federal de Uberlândia – UFU

5. Uberlândia

6. 38400-902 Brazil

7. Universidade Federal de São Carlos – UFSCar

8. São Carlos

9. 13565-905 Brazil

Abstract

The fac-[Re(CO)₃(cbz₂phen)(L)]^0/+1 complexes showed a remarkable presence of the ILCT_cbz2phen fluorescence in addition to the usually observed ³MLCT_{Re→cbz2phen}. In PMMA films the emission is completely turned into a triplet excited state manifold.

Funder

Fundação de Amparo à Pesquisa do Estado de Minas Gerais

São Paulo Research Foundation

Conselho Nacional de Desenvolvimento Científico e Tecnológico

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT01112H

Reference75 articles.

1. Nature of the lowest excited state in tricarbonylchloro-1,10-phenanthrolinerhenium(I) and related complexes