Ru(<scp>ii</scp>)/Ru(<scp>iv</scp>)-catalyzed C(sp<sup>2</sup>)–H allylation with alkene difunctionalization to access isochroman-1-imines-Reference-Cited by-同舟云学术

Ru(ii)/Ru(iv)-catalyzed C(sp²)–H allylation with alkene difunctionalization to access isochroman-1-imines

Published:2023 Issue:62 Volume:59 Page:9497-9500
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Joshi Ashish¹²,Moorthy Shruti³^ORCID,Chavada Lilesh Rambhai¹²,Singh Saurabh Kumar³^ORCID,Pandey Ashok Kumar¹²^ORCID

Affiliation:

1. Fluoro-Agrochemicals Division, CSIR-Indian Institute of Chemical Technology (CSIR-IICT), Tarnaka, Hyderabad, Telangana 500007, India

2. Chemical Science Division, Academy of Scientific and Innovative Research (AcSIR), Ghaziabad 201002, India

3. Department of Chemistry, Indian Institute of Technology Hyderabad, Kandi, Sangareddy, Telangana, 502285, India

Abstract

C(sp2)–H allylation and alkene difunctionalization were combined to access isochroman-1-imines. Experimental results and DFT analysis indicated that C–H allylation occurred via a Ru(iv)-allyl transfer (redox) mechanism instead of an olefin insertion.

Funder

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CC/D3CC01604H

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