Metal–organic layers stabilize earth-abundant metal–terpyridine diradical complexes for catalytic C

Metal–organic layers stabilize earth-abundant metal–terpyridine diradical complexes for catalytic C–H activation

Published:2018 Issue:1 Volume:9 Page:143-151
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Lin Zekai¹²³⁴,Thacker Nathan C.¹²³⁴,Sawano Takahiro¹²³⁴,Drake Tasha¹²³⁴,Ji Pengfei¹²³⁴,Lan Guangxu¹²³⁴,Cao Lingyun⁵⁶¹⁷⁸,Liu Shubin⁹¹⁰⁴,Wang Cheng⁵⁶¹⁷⁸^ORCID,Lin Wenbin¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. University of Chicago

3. Chicago

4. USA

5. Collaborative Innovation Center of Chemistry for Energy Materials

6. State Key Laboratory of Physical Chemistry of Solid Surfaces

7. College of Chemistry and Chemical Engineering

8. Xiamen University

9. Research Computing Center

10. University of North Carolina

Abstract

Metal–organic layers stabilize Fe^II or Co^II-terpyridine diradical complexes to catalyze alkylazide C_sp3–H amination and benzylic C–H borylation, respectively.

Funder

National Science Foundation

Argonne National Laboratory

University of Chicago Materials Research Science and Engineering Center

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/SC/C7SC03537C

Reference77 articles.

1. Hydrogen storage in metal–organic frameworks