Slow spin crossover in bis-meridional Fe2+ complexes through spin-state auto-adaptive N6/N8 coordination-Reference-Cited by-同舟云学术

Slow spin crossover in bis-meridional Fe2+ complexes through spin-state auto-adaptive N6/N8 coordination

Published:2018 Issue:48 Volume:47 Page:17257-17265
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Petzold Holm¹²³⁴⁵^ORCID,Hörner Gerald⁶²⁷⁵^ORCID,Schnaubelt Linda¹²³⁴⁵,Rüffer Tobias¹²³⁴⁵^ORCID

Affiliation:

1. TU Chemnitz

2. Institut für Chemie

3. Anorganische Chemie

4. 09111 Chemnitz

5. Germany

6. TU Berlin

7. 10623 Berlin

Abstract

The X-factor: Exchange of pyridine (X = N) for phenyl (X = CH) substituents renders the coordination number of Fe²⁺ complexes spin-state dependent. Slow spin-state exchange emerges through kinetic and thermodynamic stabilization of the N6(+2) high-spin state.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT03652G

Reference52 articles.

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2. Light-Induced Spin Crossover and the High-Spin→Low-Spin Relaxation

3. Spin crossover phenomena in Fe(ii) complexes