Thermal modulation of reaction equilibria controls mass transfer in CO<sub>2</sub>-binding organic liquids-Reference-Cited by-同舟云学术

Thermal modulation of reaction equilibria controls mass transfer in CO₂-binding organic liquids

Published:2023 Issue:2 Volume:16 Page:484-490
ISSN:1754-5692
Container-title:Energy & Environmental Science
language:en
Short-container-title:Energy Environ. Sci.

Author:

Moore Thomas¹^ORCID,Varni Anthony J.¹^ORCID,Pang Simon H.¹^ORCID,Akhade Sneha A.¹^ORCID,Li Sichi¹^ORCID,Nguyen Du T.¹,Stolaroff Joshuah K.²

Affiliation:

1. Lawrence Livermore National Laboratory, 7000 East Avenue, Livermore, CA, 94550, USA

2. Mote Hydrogen, Los Angeles, CA, USA

Abstract

CO2BOLs are promising CCS solvents, whose mass transfer rates improve upon cooling. We show this unintuitive behavior is due to slow transport of reaction products from the gas–liquid interface, caused by shifts in reaction equilibria.

Funder

U.S. Department of Energy

Office of Fossil Energy and Carbon Management

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Nuclear Energy and Engineering,Renewable Energy, Sustainability and the Environment,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/EE/D2EE03237F

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