Gas-phase structures of sterically crowded disilanes studied by electron diffraction and quantum chemical methods: 1,1,2,2-tetrakis(trimethylsilyl)disilane and 1,1,2,2-tetrakis(trimethylsilyl)dimethyldisilane-Reference-Cited by-同舟云学术

Gas-phase structures of sterically crowded disilanes studied by electron diffraction and quantum chemical methods: 1,1,2,2-tetrakis(trimethylsilyl)disilane and 1,1,2,2-tetrakis(trimethylsilyl)dimethyldisilane

Published:2014 Issue:26 Volume:43 Page:10175-10182
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Schwabedissen Jan¹²³,Lane Paul D.⁴⁵⁶,Masters Sarah L.⁴⁷⁸,Hassler Karl⁹¹⁰,Wann Derek A.⁴⁵⁶

Affiliation:

1. Fakultät für Chemie

2. Anorganische Chemie und Strukturchemie

3. 33615 Bielefeld, Germany

4. Department of Chemistry

5. University of York

6. Heslington, UK

7. University of Canterbury

8. Christchurch 8140, New Zealand

9. Technische Universität Graz

10. A-8010 Graz, Austria

Abstract

Structures of the two title disilanes have been determined. The presence of bulky, flexible Me₃Si groups dictates many aspects of the geometric structures.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT00628C

Reference34 articles.

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2. Bis(hypersilyl)tin and Bis(hypersilyl)lead, Two Electron-Rich Carbene Homologs

3. Electron diffraction studies of the hydrides Si2H6 and P2H4

4. The molecular structure of hexafluorodisilane, determined by gas phase electron diffraction

5. Molecular Structure and Internal Rotation of Hexachloroethane, Hexachlorodisilane, and Trichloromethyl‐Trichlorosilane

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