Origin of enantioselectivity reversal in Lewis acid-catalysed Michael additions relying on the same chiral source-Reference-Cited by-同舟云学术

Origin of enantioselectivity reversal in Lewis acid-catalysed Michael additions relying on the same chiral source

Published:2021 Issue:42 Volume:12 Page:14133-14142
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Riehl Paul S.¹^ORCID,Richardson Alistair D.¹^ORCID,Sakamoto Tatsuhiro¹,Reid Jolene P.²^ORCID,Schindler Corinna S.¹^ORCID

Affiliation:

1. Willard Henry Dow Laboratory, Department of Chemistry, University of Michigan, 930 North University Avenue, Ann Arbor, Michigan 48109, USA

2. Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, British Columbia, V6T 1Z1, Canada

Abstract

Enantiodivergence is an important concept in asymmetric catalysis that enables access to both enantiomers of a product relying on the same chiral source as reagent.

Funder

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC03741B

Reference69 articles.

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3. L.Paquette , Chiral reagents for asymmetric synthesis , Wiley , Chichester , 2008

4. Dual Enantioselective Control in Asymmetric Synthesis

5. Solvent-Dependent Enantiodivergence in the Chlorocyclization of Unsaturated Carbamates

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