Oxidative additions of alkynyl/vinyl iodides to gold and gold-catalyzed vinylation reactions triggered by the MeDalphos ligand
Author:
Affiliation:
1. Laboratoire Hétérochimie Fondamentale et Appliquée (UMR 5069)
2. Université de Toulouse (UPS)
3. CNRS
4. F-31062 Toulouse
5. France
6. Institut de Chimie de Toulouse (FR 2599)
7. 31062 Toulouse Cedex 09
Abstract
The hemilabile Ad2P(o-C6H4)NMe2 ligand promotes fast, quantitative and irreversible oxidative addition of alkynyl and vinyl iodides to gold.
Funder
Centre National de la Recherche Scientifique
European Commission
Agence Nationale de la Recherche
Université de Toulouse
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC01483H
Reference55 articles.
1. Homogeneous Gold Redox Chemistry: Organometallics, Catalysis, and Beyond
2. Oxidant-free oxidative gold catalysis: the new paradigm in cross-coupling reactions
3. Facile Oxidative Addition of Aryl Iodides to Gold(I) by Ligand Design: Bending Turns on Reactivity
4. Oxidative Addition of Carbon-Carbon Bonds to Gold
5. Stereo- and Regioselective Gold-Catalyzed Hydroamination of Internal Alkynes with Dialkylamines
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