Vibrational spectrum and photochemistry of phosphaketene HPCO-Reference-Cited by-同舟云学术

Vibrational spectrum and photochemistry of phosphaketene HPCO

Published:2021 Issue:35 Volume:23 Page:19237-19243
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Qian Weiyu¹^ORCID,Lu Bo¹,Tan Gengwen²^ORCID,Rauhut Guntram³^ORCID,Grützmacher Hansjörg⁴^ORCID,Zeng Xiaoqing¹^ORCID

Affiliation:

1. Department of Chemistry, Fudan University, 200433 Shanghai, China

2. College of Chemistry, Chemical Engineering and Materials Science, Soochow University, 215123 Suzhou, China

3. Institute for Theoretical Chemistry, University of Stuttgart, Pfaffenwaldring 55, Stuttgart 70569, Germany

4. Laboratorium für Anorganische Chemie, ETH, Zürich 8092, Switzerland

Abstract

The simplest phosphaketene HPCO has been isolated and its photochemistry has been explored using matrix-isolation IR spectroscopy. In addition to HP and its trapping product HPNO˙, the long-sought isomer HOCP has been also identified among the photolysis products of HPCO.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CP/D1CP02860J

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