The role of 3d–4f exchange interaction in SMM behaviour and magnetic refrigeration of carbonato bridged CuII2LnIII2 (Ln = Dy, Tb and Gd) complexes of an unsymmetrical N2O4 donor ligand-Reference-Cited by-同舟云学术

The role of 3d–4f exchange interaction in SMM behaviour and magnetic refrigeration of carbonato bridged CuII2LnIII2 (Ln = Dy, Tb and Gd) complexes of an unsymmetrical N2O4 donor ligand

Published:2019 Issue:40 Volume:48 Page:15170-15183
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Maity Souvik¹²³⁴⁵,Mondal Arpan¹⁶⁷⁵,Konar Sanjit¹⁶⁷⁵^ORCID,Ghosh Ashutosh¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. University College of Science

3. University of Calcutta

4. Kolkata 700009

5. India

6. Indian Institute of Science Education and Research Bhopal

7. Bhopal 462066

Abstract

The role of exchange interaction between Cu(ii) and Ln(iii) ions in SMM behaviour and magnetocaloric effects has been extensively investigated by both experimental and theoretical CASSCF/RASSI-SO/SINGLE_ANISO methods.

Funder

University Grants Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT02627D

Reference91 articles.

1. The structures and magnetic properties of complexes containing 3d- and 4f-metals

2. Toward heterometallic single-molecule magnets: Synthetic strategy, structures and properties of 3d–4f discrete complexes

3. High-Nuclearity 3d–4f Clusters as Enhanced Magnetic Coolers and Molecular Magnets