Dimethylsilyl bis(amidinate)actinide complexes: synthesis and reactivity towards oxygen containing substrates-Reference-Cited by-同舟云学术

Dimethylsilyl bis(amidinate)actinide complexes: synthesis and reactivity towards oxygen containing substrates

Published:2014 Issue:29 Volume:43 Page:11376-11387
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Karmel Isabell S. R.¹²³⁴,Elkin Tatyana¹²³⁴,Fridman Natalia¹²³⁴,Eisen Moris S.¹²³⁴

Affiliation:

1. Schulich Faculty of Chemistry

2. Institute of Catalysis Science and Technology

3. Technion – Israel Institute of Technology

4. Technion City, 32000 Israel

Abstract

Ligand1reacts with ThCl₄and UCl₄yielding complexes2and4, respectively. Complex3is obtained from complex2displaying extremely short Th–OH bond distances.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT01361A

Reference99 articles.

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3. R. J. Batrice , I.-S. R.Karmel and M. S.Eisen , Product Class 13: Organometallic Complexes of the Actinides , in Science of Synthesis Knowledge Updates 2012/4 , ed. A. Fuerstner , D. Hall , I. Marek , M. Oestreich , E. Schaumann and B. M. Stoltz , Georg Thieme Verlag KG , Stuttgart, Germany , 2013 , pp. 99–211 and reference cited therein

4. Synthesis of Uranium–Ligand Multiple Bonds by Cleavage of a Trityl Protecting Group

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