A halogenophilic pathway in the reactions of transition metal carbonyl anions with [(η6-iodobenzene)Cr(CO)3]-Reference-Cited by-同舟云学术

A halogenophilic pathway in the reactions of transition metal carbonyl anions with [(η6-iodobenzene)Cr(CO)3]

Published:2014 Issue:35 Volume:43 Page:13392-13398
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Sazonov Petr K.¹²,Ivushkin Vasiliy A.¹²,Khrustalev Victor N.³⁴²,Kolotyrkina Natal'ya G.⁵⁶⁴⁷,Beletskaya Irina P.¹²

Affiliation:

1. Chemistry Department of the M.V. Lomonosov Moscow State University

2. Moscow, Russia

3. A.N. Nesmeyanov Institute of Organoelement Compounds (INEOS)

4. Russian Academy of Sciences

5. ND Zelinsky Institute of Organic Chemistry

6. Department of Structural Studies (IOC)

7. Moscow 119991, Russia

Abstract

Formal nucleophilic substitution in [(η⁶-iodobenzene)Cr(CO)₃] begins with the attack of the carbonylmetallate at iodine to form the aryl carbanion and [IM(CO)_nL], which then give all of the variety of products observed.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT01363H

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