Rational design of solid-acid catalysts for cellulose hydrolysis using colloidal theory

Author:

Zhang Ziyang123ORCID,Tompsett Geoffrey A.123,Granados-Focil Sergio4523ORCID,Lambert Christopher R.623,Timko Michael T.123ORCID

Affiliation:

1. Department of Chemical Engineering

2. Worcester

3. USA

4. Department of Chemistry

5. Clark University

6. Department of Chemistry & Biochemistry

Abstract

DLVO analysis shows that the solid acid catalysts used for cellulose hydrolysis should maximize van der Waals attraction and minimize electrostatic repulsion. High temperature and high shear conditions can promote catalyst–cellulose interaction.

Funder

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference58 articles.

1. G. Centi and R. A.van Santen , Catalysis for renewables: from feedstock to energy production . 2008 : John Wiley & Sons

2. The pyrolytic behavior of cellulose in lignocellulosic biomass: a review

3. CELLULOSE DEGRADATION IN ANAEROBIC ENVIRONMENTS

4. D. Humbird , et al. , Process design and economics for biochemical conversion of lignocellulosic biomass to ethanol: dilute-acid pretreatment and enzymatic hydrolysis of corn stover . 2011 , National Renewable Energy Lab.(NREL) , Golden, CO (United States)

5. Substrate and Enzyme Characteristics that Limit Cellulose Hydrolysis

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