Atmospheric formation of the NO3 radical from gas-phase reaction of HNO3 acid with the NH2 radical: proton-coupled electron-transfer versus hydrogen atom transfer mechanisms-Reference-Cited by-同舟云学术

Atmospheric formation of the NO3 radical from gas-phase reaction of HNO3 acid with the NH2 radical: proton-coupled electron-transfer versus hydrogen atom transfer mechanisms

Published:2014 Issue:36 Volume:16 Page:19437-19445
ISSN:1463-9076
Container-title:Phys. Chem. Chem. Phys.
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Anglada Josep M.¹²³,Olivella Santiago¹²³,Solé Albert⁴⁵⁶

Affiliation:

1. Departament de Química Biològica i Modelització Molecular

2. (IQAC – CSIC)

3. E-08034 Barcelona, Spain

4. Departament de Química Física i Institut de Química Teòrica i Computacional (IQTCUB)

5. Universitat de Barcelona

6. E-08028 Barcelona, Spain

Abstract

The amidogen radical abstracts the hydrogen from nitric acid through a proton coupled electron transfer mechanism rather than by an hydrogen atom transfer process.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2014/CP/C4CP02792B

Reference81 articles.

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3. Evaluated Kinetic and Photochemical Data for Atmospheric Chemistry: Supplement VI. IUPAC Subcommittee on Gas Kinetic Data Evaluation for Atmospheric Chemistry

4. Simultaneous Kinetics and Ring-down: Rate Coefficients from Single Cavity Loss Temporal Profiles

5. The question of a pressure effect in the reaction OH + HNO3. A laser flash-photolysis resonance-absorption study

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