Selective anomeric acetylation of unprotected sugars in water-Reference-Cited by-同舟云学术

Selective anomeric acetylation of unprotected sugars in water

Published:2017 Issue:3 Volume:8 Page:1896-1900
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Lim David¹²³⁴^ORCID,Fairbanks Antony J.¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. University of Canterbury

3. Christchurch

4. New Zealand

5. Biomolecular Interaction Centre

Abstract

Selective acetylation of only the anomeric hydroxyl group of unprotected sugars is possible in aqueous solution. This new one step route to glycosyl acetates may facilitate their use as donors for enzyme catalysed glycosylation.

Funder

University of Canterbury

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/SC/C6SC04667C

Reference42 articles.

1. Regioselective modification of unprotected glycosides

2. Unprotected Carbohydrates as Starting Material in Chemical Synthesis: Not Just a Challenge but an Opportunity

3. Ueber die Glucoside der Alkohole

4. Mechanism in carbohydrate chemistry

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