Establishing carbon–carbon double bond position and configuration in unsaturated fatty acids by gas-phase infrared spectroscopy

Author:

Kirschbaum Carla12ORCID,Young Reuben S. E.34ORCID,Greis Kim12ORCID,Menzel Jan Philipp35ORCID,Gewinner Sandy2,Schöllkopf Wieland2ORCID,Meijer Gerard2ORCID,von Helden Gert2ORCID,Causon Tim6ORCID,Narreddula Venkateswara R.35,Poad Berwyck L. J.345ORCID,Blanksby Stephen J.345ORCID,Pagel Kevin12ORCID

Affiliation:

1. Institut für Chemie und Biochemie, Freie Universität Berlin, Altensteinstraße 23a, 14195 Berlin, Germany

2. Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, 14195 Berlin, Germany

3. School of Chemistry and Physics, Queensland University of Technology, Brisbane, QLD 4000, Australia

4. Central Analytical Research Facility, Queensland University of Technology, Brisbane, QLD 4000, Australia

5. Centre for Materials Science, Queensland University of Technology, Brisbane, QLD 4000, Australia

6. Institute of Analytical Chemistry, University of Natural Resources and Life Sciences Vienna, 1190 Vienna, Austria

Abstract

3-Pyridylcarbinol ester derivatization introduces a universal probe for cryogenic gas-phase infrared spectroscopy of fatty acids that enables assignment of the position and configuration of carbon–carbon double bonds even in the presence of isomers.

Funder

Fonds National de la Recherche Luxembourg

Australian Education International, Australian Government

H2020 European Research Council

Australian Research Council

Australian Government

Fonds der Chemischen Industrie

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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