Synthesis of chiral boranes <i>via</i> asymmetric insertion of carbenes into B–H bonds catalyzed by the rhodium(<scp>i</scp>) diene complex-Reference-Cited by-同舟云学术

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Synthesis of chiral boranes via asymmetric insertion of carbenes into B–H bonds catalyzed by the rhodium(i) diene complex

Published:2024 Issue:65 Volume:60 Page:8601-8604
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Ankudinov Nikita M.¹^ORCID,Komarova Alina A.¹,Podyacheva Evgeniya S.¹²,Chusov Denis A.¹²^ORCID,Danshina Anastasia A.³,Perekalin Dmitry S.¹²^ORCID

Affiliation:

1. A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilova str., 119334, Moscow, Russia

2. National Research University Higher School of Economics, 7 Vavilova str., 117312, Moscow, Russia

3. N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russia

Abstract

Catalytic insertion of diazo compounds into B–H bonds produces unique compounds with tetrahedral chiral boron atoms.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D4CC02969K

Reference21 articles.

1. Stereoselective formation of boron-stereogenic organoboron derivatives

2. Recent advances in the construction of tetracoordinate boron compounds

3. Catalytic enantioselective synthesis of boron-stereogenic BODIPYs

4. Catalytic Enantioselective Construction of Chiroptical Boron-Stereogenic Compounds

5. Boron‐Based Enantiomerism

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