Long magnetic relaxation time of tetracoordinate Co2+ in imidazo[1,5-a]pyridinium-based (C13H12N3)2[CoCl4] hybrid salt and [Co(C13H12N3)Cl3] molecular complex-Reference-Cited by-同舟云学术

Long magnetic relaxation time of tetracoordinate Co2+ in imidazo[1,5-a]pyridinium-based (C13H12N3)2[CoCl4] hybrid salt and [Co(C13H12N3)Cl3] molecular complex

Published:2019 Issue:30 Volume:48 Page:11278-11284
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Vassilyeva Olga Yu.¹²³⁴^ORCID,Buvaylo Elena A.¹²³⁴,Kokozay Vladimir N.¹²³⁴,Skelton Brian W.⁵⁶⁷⁸⁹,Rajnák Cyril¹¹⁰¹¹¹²¹³^ORCID,Titiš Ján¹¹⁰¹¹¹²¹³^ORCID,Boča Roman¹¹⁰¹¹¹²¹³^ORCID

Affiliation:

1. Department of Chemistry

2. Taras Shevchenko National University of Kyiv

3. Kyiv 01601

4. Ukraine

5. School of Molecular Sciences

6. Chemistry M310

7. the University of Western Australia

8. Perth

9. Australia

10. Faculty of Natural Sciences

11. University of SS Cyril and Methodius

12. 91701 Trnava

13. Slovakia

Abstract

Co(ii) SIMs with simple tetrahedral environments and low positive magnetic anisotropy are unique with respect to the remarkably long relaxation time for a given applied DC field and temperature.

Funder

Agentúra na Podporu Výskumu a Vývoja

Ministry of Education and Science of Ukraine

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT01642B

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1. The rise of 3-d single-ion magnets in molecular magnetism: towards materials from molecules?

2. First principles approach to the electronic structure, magnetic anisotropy and spin relaxation in mononuclear 3d-transition metal single molecule magnets